Oxidation Derived PANI/MgO Nanocomposites : Electrical and Sensors Study
Main Article Content
Abstract
Nanosized metal oxide dispersed polymer nanocomposites constitute a new class of polymeric materials finds enhanced properties and applications. The present work aims to prepare MgO dispersed polyaniline nanocomposite (MgO/PANI) and also its properties. Insitu chemical oxidative polymerisation method with ammonium per sulphate as an oxidising agent is used for the preparation of PANI/MgO nanocomposites. The reaction was catalysed by hydrochloric acid and also different weight percentage of MgO is maintained with same PANI for different nanocomposites. Structural characterisation of the said composites was carried out by X-ray diffraction tool and the morphology by Scanning Electron microscope (SEM) respectively. AC electrical conductivity of PANI/MgO nanocomposites were well studied and deliberate with the help of equivalent hotness. Further, it demonstrates an corroboration for the transport property of PANI /MgO nanocomposite. Sensor study for the composite is also undertaken with different gases to know its sensing behaviour.
Article Details
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
References
K Namsheer, CS Rout; Conducting polymers: a comprehensive review on recent advances in synthesis, properties and applications. RSC Adv 11 (2021), 5659-5697. https://doi.org/10.1039/d0ra07800j
MT Ramesan, V Santhi; Synthesis, characterization, conductivity and sensor application study of polypyrrole/silver doped nickel oxide nanocomposites, Compos. Interfaces 25 (2018), 725-741. https://doi.org/10.1080/09276440.2018.1439626
L Jiang, S Zhang, SA Kulinich, X Song, J Zhu, X Wang, H Zeng; Optimizing hybridization of 1T and 2H phases in MoS2 monolayers to improve capacitances of super capacitors, Mater Res Lett 3 (2015), 177-183. https://doi.org/10.1080/21663831.2015.1057654
J Wilson, S Radhakrishnan, C Sumathi, V Dharuman; Polypyrrole-polyaniline-Au (PPy-PANi-Au) nano composite films for label-free electrochemical DNA sensing, Sensors Actuators, B Chem 171-172 (2012), 216-222. https://doi.org/10.1016/j.snb.2012.03.019
MS Tamboli, MV Kulkarni, SP Deshmukh, BB Kale; Synthesis and spectroscopic characterisation of silver-polyaniline nanocomposite, Mater Res Innov 17 (2013), 112-116.
https://doi.org/10.1179/1433075X12Y.0000000037
NM Barkoula, B Alcock, NO Cabrera, T Peijs; Flame-retardancy properties of intumescent ammonium poly (phosphate) and mineral filler magnesium hydroxide in combination with graphene, Polym Polym Compos 16 (2008), 101-113. https://doi.org/10.1177/096739110801600203
R Prabhu, T Jeevananda, KR Reddy, AV Raghu; Polyaniline-fly ash nanocomposites synthesized via emulsion polymerization: physicochemical, thermal and dielectric properties, Mater Sci Energy Technol 4 (2021),107-112. https://doi.org/10.1016/j.mset.2021.02.001
SA Ture, SD Pattathil, VB Patil; Synthesis and fluorescence sensing of energetic materials using benzenesulfonic acid-doped polyaniline, J Mater Sci 33 (2022), 8551-8565. https://doi.org/10.1007/s10854-021-06537-7
JL Wojkiewicz, VN Bliznyuk, S Carquigny, N Elkamchi, N Redon, T Lasri, AA Pud; Sensors and Actuators B : chemical nanostructure polyaniline-based composites for ppb range ammonia sensing, Sensors Actuators B Chem 160 (2011), 1394-1403. https://doi.org/10.1016/j.snb.2011.09.084
V.B. Patil, M.N. Nadagouda, S.A. Ture, C. V Yelamaggad, V. Abbaraju; Detection of energetic materials via polyaniline and its different modified forms, Polym Adv Technol (2021), 1-15. https://doi.org/10.1002/pat.5458
S.A. Ture, V. Abbaraju; Understanding of mechanistic perspective in sensing of energetic nitro compounds through spectroscopic and electrochemical studies, J. Appl Polym Sci, (2021) 1-14. https://doi.org/10.1002/app.50776
VB Patil, SA Ture, CV Yelamaggad, MN Nadagouda, A Venkataraman; Turn-off fluorescent sensing of energetic materials using protonic acid doped polyaniline: a spectrochemical mechanistic approach, Zeitschrift Fur Anorg. Und Allg. Chemie, 647 (2021), 331-340. https://doi.org/10.1002/zaac.202000321
L Chen, Y Zhai, H Ding, G Zhou, Y Zhu, D Hui; Preparation, characterization and thermoelectricity of ATT/TiO 2/PANI nano-composites doped with different acids, Compos Part B Eng 45 (2013), 111-116. https://doi.org/10.1016/j.compositesb.2012.02.028
MC Arenas, G Sánchez, O Martínez-álvarez, VM Castaño; Composites : Part B Electrical and morphological properties of polyaniline – polyvinyl alcohol in situ nanocomposites, Compos Part B 56 (2014), 857-861. https://doi.org/10.1016/j.compositesb.2013.09.010
A Fattoum, Z Ben Othman, M Arous; Dc and Ac conductivity of polyaniline/poly (methyl methacrylathe) blends below the percolation threshold, Mater Chem Phys 135 (2012), 117-122. https://doi.org/10.1016/j.matchemphys.2012.04.033
CS Park, C Lee, OS Kwon; Conducting polymer based nanobiosensors, Polymers (Basel) 8 (2016), 1-18. https://doi.org/10.3390/polym8070249
NF Zaaba, H Ismail; Thermoplastic/natural filler composites: a short review, J Phys Sci 30 (2019), 81-99. https://doi.org/10.21315/jps2019.30.s1.5
S. Liu, S.K. Tam, K.M. Ng; Dual-reductant synthesis of nickel nanoparticles for use in screen-printing conductive paste, J. Nanoparticle Res. 23 (2021). https://doi.org/10.1007/s11051-021-05191-8
N Singh, P Kumar, S Mridula, S Poonam, T Saurabh, K Singh; Fabrication and characterization of polyaniline, polyaniline/MgO (30%) and polyaniline/MgO (40%) nanocomposites for their employment in LPG sensing at room temperature, J Mater Sci Mater Electron (2019). https://doi.org/10.1007/s10854-019-00737-y
M. Salehipour, S. Rezaei, J. Mosafer, Z. Pakdin-Parizi, A. Motaharian, M. Mogharabi-Manzari; Recent advances in polymer-coated iron oxide nanoparticles as magnetic resonance imaging contrast agents, J Nanoparticle Res 23 (2021). https://doi.org/10.1007/s11051-021-05156-x
R Gupta, P Bhardwaj, D Mishra, M Prasad, SS Amritphale; Formulation of mechanochemically evolved fly ash based hybrid inorganic–organic geopolymers with multilevel characterization, J Inorg Organomet Polym Mater 27 (2017), 385-398. https://doi.org/10.1007/s10904-016-0461-0
HD Tran, Y Wang, JM D’Arcy, RB Kaner; Toward an understanding of the formation of conducting polymer nanofibers, ACS Nano 2 (2008), 1841-1848. https://doi.org/10.1021/nn800272z
K Pandiselvi, A Manikumar, S Thambidurai; Synthesis of novel polyaniline/MgO composite for enhanced adsorption of reactive dye, J Appl Polym Sci 131 (2014), 1-9. https://doi.org/10.1002/app.40210
R Wahab, SG Ansari, MA Dar, YS Kim, HS Shin; Synthesis of magnesium oxide nanoparticles by sol-gel process, Mater Sci Forum 558-559 (2007): 983-986. https://doi.org/10.4028/www.scientific.net/msf.558-559.983
J. Husain, N. Reddy, A. Begum, S. Farheen, S.M. Nayak, G. Shivaraj, G. Mathad, D. Pathar; Conductivity and LPG sensing behavior of PANI/MgO nano composites thin films, Mater Today Proc (2020) 2-4. https://doi.org/10.1016/j.matpr.2020.09.338
NZ Al-Hazeem, NM Ahmed; Effect of addition of polyaniline on polyethylene oxide and polyvinyl alcohol for the fabrication of nanorods, ACS Omega 5 (2020), 22389-22394. https://doi.org/10.1021/acsomega.0c02802
BL Zhang, Y Long, Z Chen, M Wan; The effect of hydrogen bonding on self-assembled polyaniline nanostructures, Adv Fun Mat 100080 (2004), 693-698. https://doi.org/10.1002/adfm.200305020
S. Min, Æ.F. Wang, Æ.Y. Han; An investigation on synthesis and photocatalytic activity of polyaniline sensitized nanocrystalline TiO2 composites, J Mater Sci (2007) 9966-9972. https://doi.org/10.1007/s10853-007-2074-z
W Feng, E Sun, A Fujii, H Wu, K Niihara, K Yoshino; Synthesis and characterization of photoconducting polyaniline-TiO2 nanocomposite, Bull Chem Soc Jpn 73 (2000), 2627-2633. https://doi.org/10.1246/bcsj.73.2627
V Eskizeybek, F Sarı, H Gülce, A Gülce, A Avcı; Applied Catalysis B : environmental preparation of the new polyaniline/ZnO nanocomposite and its photocatalytic activity for degradation of methylene blue and malachite green dyes under UV and natural sun lights irradiations, Applied Catal. B, Environ 119-120 (2012), 197-206. https://doi.org/10.1016/j.apcatb.2012.02.034
V Divya, MV Sangaranarayanan; A facile synthetic strategy for mesoporous crystalline copper – polyaniline composite, Eur Polym J 48 (2012), 560-568. https://doi.org/10.1016/j.eurpolymj.2011.12.009
G Venugopal, R George, N Raghavan, T Srinivas; Structural and mechanical properties of MgO-poly(vinyl alcohol) nanocomposite film, Adv Sci Eng Med 7 (2015), 1-8. https://doi.org/10.1166/asem.2015.1714
K Mageshwari, R Sathyamoorthy, PS Patil; Template-free synthesis of MgO nanoparticles for effective photocatalytic applications, Powder Technol 249 (2013), 456-462. https://doi.org/10.1016/j.powtec.2013.09.016
LUM Jamal, M Jaffar; Green synthesis of MgO nanoparticles and it antibacterial activity, Iran J Sci Technol Trans A Sci (2016). https://doi.org/10.1007/s40995-016-0041-8
H Ahmed, HM Abduljalil, A Hashim; Structural, optical and electronic properties of novel (PVA – MgO)/SiC nanocomposites films for humidity sensors, Trans Electr Electron Mater (2019). https://doi.org/10.1007/s42341-019-00111-z
G Mohammed, AM El, WM Morsi; Spectroscopic, thermal, and electrical properties of MgO/polyvinyl pyrrolidone/polyvinyl alcohol nanocomposites, J Phys Chem Solids 115 (2018), 238-247. https://doi.org/10.1016/j.jpcs.2017.12.050
SF Bdewi, OG Abdullah, BK Aziz, AAR Mutar; Synthesis, structural and optical characterization of MgO nanocrystalline embedded in PVA matrix, J Inorg Organomet Polym Mater 26 (2016), 326-334. https://doi.org/10.1007/s10904-015-0321-3
R. Ullah; Ternary composites of polyaniline with polyvinyl alcohol and Cu by inverse emulsion polymerization : a comparative study, Adv Polym Technol. (2018) 1-12. https://doi.org/10.1002/adv.22129
N. Jamil, M. Mehmood, A. Lateef, R. Nazir, N. Ahsan; ; MgO Nanoparticles for the removal of reactive dyes from wastewater MgO nanoparticles for the removal of reactive dyes from wastewater synthesis of adsorbent, advanced materials, Tech Connect Briefs (2015) 978-1-4987-4727-1.
MM Imani, M Safaei; Optimized synthesis of magnesium oxide nanoparticles as bactericidal agents, J Nanotech (2019). https://doi.org/10.1155/2019/6063832
N Singh, S Chand, M Taunk; Facile in-situ synthesis, microstructural, morphological and electrical transport properties of polypyrrole-cuprous iodide hybrid nanocomposites, J Solid State Chem 303 (2021), 122501. https://doi.org/10.1016/j.jssc.2021.122501
Synthesis and characterization of novel bio-nanocomposite of polyvinyl alcohol-Arabic gum-magnesium oxide via direct blending method, Carbohydr Polym 260 117802. https://doi.org/10.1016/j.carbpol.2021.117802
J Bhadra, NJ Al-Thani, NK Madi, MA Al-Maadeed; Effects of aniline concentrations on the electrical and mechanical properties of polyaniline polyvinyl alcohol blends, Arab J Chem 10 (2017) 664-672. https://doi.org/10.1016/j.arabjc.2015.04.017