Cerium Based Uio-66 Chemiresistor for the Detection of Carbon Dioxide

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Published: Dec 15, 2021
Keywords:
Metal-Organic Frameworks, Chemiresistive gas sensing, Carbon dioxide, Cerium, Redox active.

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Marilyn Esclance DMello
Materials Science and Catalysis Division Poornaprajna Institute of Scientific Research, Bengaluru, Karnataka, India
Suresh Babu Kalidindi
Department of Inorganic and Analytical Chemistry Andhra University, Visakhapatnam, Andhra Pradesh, India.

Abstract

Metal-Organic Frameworks are a versatile class of hybrid materials that can offer tantalizing opportunities to tune its structure, chemical composition suitable for gas sensing application. CO2 - a major greenhouse gas emission is challenging due to its low reactivity. Hence, sensors with more adsorption/ reactive sites and CO2 activating sites are needed to develop effective CO2 sensors. Chemiresistive sensors that are based on change in electrical properties (resistance/ conductance) offer simpler instrumentation and are cost effective over other sensing technologies. The surge to develop effective CO2 sensors have allowed us to demonstrate a simple chemiresistor- UiO-66 (Ce). UiO-66 (Ce) was synthesized and characterized by powder X-ray diffraction, scanning electron microscopy and nitrogen sorption studies. The UiO-66 (Ce) showed a very high response of 88 % at 150 °C. By combining the well-known features of redox active Ce with UiO-66 based MOF, we have converted an innocent MOF into an effective chemiresistive CO2 sensor. The gas sensing characteristics can be attributed to a greater number of active sites for CO2 sensing on replacement of Zr with Ce in the nodes of UiO-66.

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Marilyn Esclance DMello, Suresh Babu Kalidindi. Cerium Based Uio-66 Chemiresistor for the Detection of Carbon Dioxide. J. Int. Acad. Phys. Sci. [Internet]. 2021 Dec. 15 [cited 2024 May 19];25(4):567-7. Available from: https://www.iaps.org.in/journal/index.php/journaliaps/article/view/901
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Vol. 25 No. 4 (2021): Table of Content
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